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Bleaching


Bleaching Process: Whiteness, as a comparison to a standard, is measured in a 100 pt range.

Bleached, sulfite pulp can achieve a value of 94% ISO when tested on a Zeiss reflectance meter, and unbleached alkaline stock may be 15% ISO as a comparison.  This is the characteristic brown, corrugated paper found in bags and cartons. So-called chromophoric group on the lignin are responsible for color. The fibers themselves, the cellulose and hemi-cellulose are inherently white and do not contribute to the color. Hence, the strategy of bleaching is to destroy these chromophoric groups.  There are two principal methods in bleaching. One is to selectively destroy the chromophoric groups on the lignin while leaving the lignin itself intact. This is generally referred to as ‘brightening’ and is more common on mechanical pulps that have high lignin content. Brightening however does not have a permanent effect; exposure to light causes lignin to dicolor as can be observed with old newspapers. True bleaching removes all residual lignin and allows stable white pulps to be produced.

Whiteness, as a comparison to a standard, is measured in a 100 pt range. Bleached, sulfite pulp can achieve a value of 94% ISO when tested on a Zeiss reflectance meter, and unbleached alkaline stock may be 15% ISO as a comparison. This is the characteristic brown, corrugated paper found in bags and cartons. So-called chromophoric group on the lignin are responsible for color. The fibers themselves, the cellulose and hemi-cellulose are inherently white and do not contribute to the color. Hence, the strategy of bleaching is to destroy these chromophoric groups. There are two principal methods in bleaching. One is to selectively destroy the chromophoric groups on the lignin while leaving the lignin itself intact. This is generally referred to as ‘brightening’ and is more common on mechanical pulps that have high lignin content. Brightening however does not have a permanent effect; exposure to light causes lignin to dicolor as can be observed with old newspapers. True bleaching removes all residual lignin and allows stable white pulps to be produced.  
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Process Related Products
ARC Composites
Use Product Description
bleach plants ARC FCS 600 Used to Protect Flooring 
bleach plants ARC FCS 601 Flooring Protection 
bleaching areas ARC S3  
Causticizing Areas ARC S3  
chemical containment ARC 791  
chemical containment ARC CS2  
chemical containment ARC CS4  
Chemical Process Pumps ARC 982  
Floors ARC SRS  
Stock Pump ARC 890  
Mechanical Packing
Use Product Description
Caustic Pump 1760 Packing  
Caustic Pump 477-1T Pump Packing  
Chemical Process Pumps 1730 Mill Pack™  
Chemical Process Pumps 1830 Packing  
Chlorine Dioxide 1830 Packing  
Pulp 1760 Packing  
Pulp 1830 Packing  
Mechanical Seals
Use Product Description
Chlorine Dioxide S20 Dual Cassette Seal Use SC/SC-SC/SC - K2037 TI and 53,54 
Pulp S10 Cassette Seal Use SC/SC - AFL and Plan 33 
Stock pumps 180 Use SC/SC EPR with Plan 62/33 
Water Pump S10 Cassette Seal Use SC/SC - AFL and Plan 13 
Technical Products
Use Product Description
Equipment (all types) 740 Heavy Duty Rust Guard  
Threaded assemblies 725 Nickel Anti-Seize Compound  
Threaded assemblies 785 Parting Lubricant  
Threaded assemblies 900 GoldEnd® Paste  
Process Related Product Case Histories
Case History Report:
CHS20040925-0025

Equipment: Suction fan

Problem: Exposure: PH 4.5. Temp. 50°C - 60°C Chlorides and high humidity Problem: The production was changed. This resulted in the fluid having a lower pH and a higher temperature. Due to these environmental changes, heavy corrosion has occurred on the suction fans. Some of these fans are 15 years old. A new acid-proof fan will cost $20,000 (USD).
 
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